As we seek more efficient utilization of waste thermal energy, use of “phase change materials (PCMs)” is a good option. PCMs have a large latent heat capacity and the ability to store-and-release heat as they change from one state of matter to another. Among many PCMs, sugar alcohols (SAs), a class of organic compounds commonly used as sweeteners, stand out due to their low cost, non-toxic, non-corrosive, and biodegradable nature.
In particular, SAs generally have their melting point in 100–200 °C, which is an important temperature range where a huge amount of waste heat exists but is currently being discarded in our world.
However, SAs usually suffer from the issue of supercooling where, instead of solidifying, they remain in a liquid state even at temperatures well below the melting point. The supercooling degrades the quality (or “exergy”) of stored thermal energy because thermal energy at lower temperature has less usefulness. (Note: Thermal energy at room temperature is totally useless, no matter how much of it exists.)
Now, in a new study, researchers from Tokyo Institute of Technology (Tokyo Tech) led by Professor Yoichi Murakami have discovered that confining SAs in covalent organic framework (COF) crystals effectively resolves the issue of supercooling. Their findings, published in the journal Materials Horizons, have the potential to revolutionize SAs as heat-storage materials.
Dr. Murakami, who is a Professor at the Laboratory for Zero-Carbon Energy at Tokyo Tech, explains, “We propose a new materials concept with which the stored thermal energy can be retrieved at a much higher temperature than before, by largely mitigating the long-standing issue of supercooling that degrades the stored thermal energy. We have created a new class of solid-state PCMs based on abundant, non-toxic, and low-cost SAs.”
2023-09-18 21:24:03
Original from phys.org rnrn